Published in
Royal Society of Chemistry, Chemical Communications, 90(51), p. 16194-16196, 2015
DOI: 10.1039/c5cc05675f
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Platinum nanoparticles in suspension are as efficient as Karstedt's complex for alkene hydrosilylation
Journal article published in 2015 by
Thomas Galeandro-Diamant,
Marie-Line Zanota,
Reine Sayah,
Laurent Veyre,
Clémence Nikitine 
,
Claude de Bellefon,
Sébastien Marrot,
Valérie Meille,
Chloé Thieuleux
,
Claude de Bellefon,
Sébastien Marrot,
Valérie Meille,
Chloé Thieuleux
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Abstract
1–2 nm Pt nanoparticles and Karstedt's catalyst were used in the hydrosilylation of 1-octene with a polymethylhydrosiloxane and showed a very similar behaviour (the same TONs and the same selectivity towards 1-octene isomerization). This further assesses that Karstedt's catalyst is not truly homogeneous, but rather colloidal, during catalysis at high TONs.