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Royal Society of Chemistry, Chemical Communications, 17(47), p. 5022, 2011

DOI: 10.1039/c1cc10741k

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Simple synthetic routes to ruthenium–indenylidene olefin metathesis catalysts

Journal article published in 2011 by César Alejandro Urbina-Blanco, Simone Manzini, Jessica Pérez Gomes, Angelino Doppiu, Steven P. Nolan ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

An efficient synthetic protocol involving reactions between the free carbene and [RuCl(2)(PPh(3))(2)(Ind)] followed by addition of pyridine leads to the isolation of olefin metathesis active [RuCl(2)(L)(Py)(Ind)] (L = SIMes and SIPr) complexes. This novel approach circumvents the use of costly tricyclohexylphosphine.