Published in
Royal Society of Chemistry, Chemical Communications, 19, p. 2194
DOI: 10.1039/b800571k
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The 8 : 1 : 1 ternary hybrid framework in the system [EDT-TTF˙+][1,4-bis(iodoethynyl)benzene][Re6Se8(CN)6]4−: dual noncovalent expression of the octahedral halogen-bond hexa-acceptor nanonode
Journal article published in 2008 by
Anne-Lise Barrès,
Abdelkrim El-Ghayoury 
,
Leokadiya V. Zorina,
Enric Canadell,
Pascale Auban-Senzier,
Patrick Batail
,
Leokadiya V. Zorina,
Enric Canadell,
Pascale Auban-Senzier,
Patrick Batail
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Abstract
Complementary shapes of the neutral symmetrical halogen-bond bis-donor core and octahedral inorganic cluster core prevent halogen-bonded polymers developing in more than one direction, favouring further templating by conducting radical cation slabs and yielding an 8 : 1 : 1 phase formulation instead of n : 2 : 1, with a 2D net, or m : 3 : 1, with a pseudo-cubic architecture, which may in principle also be targeted.