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Royal Society of Chemistry, Dalton Transactions, 14, p. 2059-2061, 2004

DOI: 10.1039/b408461f

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Mild mono and double demethylation in dimethylsulfonium substituted ruthenacarborane complexes. A regioselective reaction

Journal article published in 2004 by José Giner Planas, Clara Vi�as, Clara Viñas, Francesc Teixidor ORCID, Michael B. Hursthouse, Mark E. Light
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Reaction of [RuCl2(eta(6)-C6H6)](2) with [10-(CH3)(2)S-7,8-nido-C2B9H10](-) or [9-(CH3)(2)S-7,8-nido-C2B9H10](-) afforded the expected cationic complexes [Ru(eta(5)-n-(CH3)(2)S-7,8-C2B9H10)(eta(6)-C6H6)](+) (n=10, (1); 9, (3)), but also the unexpected neutral Ru(eta(5)-10-HS-7,8-C2B9H10)(eta(6)-C6H6) (2) or Ru(eta(5)-9-(CH3)S-7,8-C2B9H10)(eta(6)-C6H6) (4) by double and mono demethylation of the (CH3)(2)S moiety, respectively.