Published in
Royal Society of Chemistry, Organic and Biomolecular Chemistry, 37(13), p. 9659-9664, 2015
DOI: 10.1039/c5ob01523e
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Unsymmetrical 1,1-diborated multisubstituted sp3-carbons formed via a metal-free concerted-asynchronous mechanism
Journal article published in 2015 by
Ana B. Cuenca,
Jessica Cid,
Diego García-López,
Jorge J. Carbó,
Elena Fernández 
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Abstract
We have experimentally proved and computationally rationalized the unsymmetrical 1,1-diboration of diazo compounds, formed in situ from aldehydes and cyclic and non-cyclic ketones, in the absence of any transition metal complex.