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Royal Society of Chemistry, Chemical Communications, 1(52), p. 100-103, 2016

DOI: 10.1039/c5cc07101a

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Mechanistic insight into proton-coupled mixed valency

Journal article published in 2016 by Luke A. Wilkinson ORCID, Kevin B. Vincent, Anthony J. H. M. Meijer ORCID, Nathan J. Patmore
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Stabilisation of the mixed-valence state in [Mo2(TiPB)3(HDOP)]2+ (HTiPB = 2,4,6-triisopropylbenzoic acid, H2DOP = 3,6-dihydroxypyridazine) by electron transfer (ET) is related to the proton coordinate of the bridging ligands.