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Royal Society of Chemistry, Chemical Communications, 83(50), p. 12572-12574, 2014

DOI: 10.1039/c4cc05556j

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Freezing-induced ordering of block copolymer micelles

Journal article published in 2014 by Jérémy Dhainaut, Giulia Piana, Sylvain Deville ORCID, Christian Guizard, Michaela Klotz
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This paper is available in a repository.

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Abstract

We demonstrate here the ordering of block copolymer micelles by ice templating, below 0 degrees C. We used this for the preparation of silica monoliths that present an ice-templated macroporosity, combined with a 2D hexagonal mesostructure templated by the addition of P123. We propose a mechanism triggered by the progressive freezing-induced concentration.