Published in
Royal Society of Chemistry, CrystEngComm, 1(14), p. 75-78
DOI: 10.1039/c1ce06006f
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In situ formation of new organic ligands to construct two novel self-charge-transfer Pb(ii)-based frameworks
Journal article published in 2012 by
Yi Liu,
Melvin Wei Jun Tan,
Melvin Jun Wei Tan,
Melvin Jun Wei Tan,
Fengxia Wei,
Yufeng Tian,
Tom Wu,
Christian Kloc,
Fengwei Huo,
Qingyu Yan,
Huey Hoon Hng 
,
Jan,
Jan Ma,
Qichun Zhang
,
Jan,
Jan Ma,
Qichun Zhang
This paper is available in a repository.
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Abstract
Employing in situ-formed new organic ligands, two Pb(II)-based metal–organic frameworks were synthesized. Compound 1 possesses a 3D framework while compound 2 has a layered structure. Solid state UV-visible absorptions indicate that the two compounds are semiconductors with band gaps of 1.70 and 1.78 eV. Magnetic properties reveal that they are temperature-independent diamagnetic.