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Royal Society of Chemistry, Dalton Transactions, 39(43), p. 14517-14519, 2014

DOI: 10.1039/c4dt01933d

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An iron(ii) complex featuring κ3 and labile κ2-bound PNP pincer ligands – striking differences between CH2 and NH spacers

Journal article published in 2014 by Bernhard Bichler, Mathias Glatz, Berthold Stöger, Kurt Mereiter, Luis F. Veiros ORCID, Karl Kirchner ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

By changing the spacer between the pyridine and the PPh2 unit from CH2 to NH the cationic octahedral complex [Fe(κ3-P,N,P-PNP)(κ2-P,N-PNP)Cl]+ featuring a κ2-P,N bound PNP ligand instead of [Fe(κ3-P,N,P-PNP)Cl2] is formed when FeCl2 is reacted with a PNP-Ph ligand.