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Royal Society of Chemistry, Dalton Transactions, 31(43), p. 11803-11806, 2014
DOI: 10.1039/c4dt01551g
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Mechanistic insights into hydride transfer for catalytic hydrogenation of CO2 with cobalt complexes
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Abstract
The catalytic hydrogenation of CO2 to formate by Co(dmpe)2H can proceed via direct hydride transfer or via CO2 coordination to Co followed by reductive elimination of formate.