Published in
Royal Society of Chemistry, Physical Chemistry Chemical Physics, 44(16), p. 24188-24193, 2014
DOI: 10.1039/c4cp02633k
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Aromatic–hydroxyl interaction of an alpha-aryl ether lignin model-compound on SBA-15, present at pyrolysis temperatures
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Abstract
BPEa hydrogen bonds to SBA-15 surface hydroxylsviaan aromatic–hydroxyl interaction characterized by a redshift of >100 cm−1in the OH and CH vibrational frequencies. Surprisingly, this aromatic–hydroxyl interaction is present until ∼400 °C.