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Royal Society of Chemistry, Chemical Communications, 52(50), p. 6839

DOI: 10.1039/c4cc00727a

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A triangular triplatinum(0) complex with bridging germylene ligands: insertion of alkynes into the Pt–Ge bond rather than the Pt–Pt bond

Journal article published in 2014 by Makoto Tanabe ORCID, Kimiya Tanaka, Shumpei Omine, Kohtaro Osakada ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

A triangular triplatinum(0) complex with bridging germylene ligands was prepared and fully characterized. The Pt3Ge3 core is bonded with electron-releasing GePh2 and PMe3 ligands. Insertion of alkyne into the Pt–Ge bonds results in the formation of germaplatinacyclic compounds.