Published in
Royal Society of Chemistry, Dalton Transactions, 9(43), p. 3479-3491, 2014
DOI: 10.1039/c3dt52552j
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Mixed anhydride complexes of rhodium(i) and ruthenium(ii) – their synthesis and ligand rearrangements
Journal article published in 2014 by
Jacorien Coetzee,
Graham R. Eastham,
Alexandra M. Z. Slawin 
,
David J. Cole-Hamilton
,
David J. Cole-Hamilton
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Abstract
The coordination chemistry and solution behaviour of Rh(i) and Ru(ii) complexes derived from mixed anhydride ligands were explored. Mixed anhydride complexes rearrange in solution via a number of pathways and plausible mechanisms for some of the rearrangements are proposed.