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Royal Society of Chemistry, Physical Chemistry Chemical Physics, 6(13), p. 2111-2113

DOI: 10.1039/c0cp01670e

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Autocatalytic sonolysis of iron pentacarbonyl in room temperature ionic liquid [BuMeIm][Tf2N]

Journal article published in 2010 by Lenaïc Lartigue, Rachel Pflieger, Rachel Pfliegler, Sergey I. Nikitenko, Yannick Guari, Lorenzo Stievano, Moulay Tahar Sougrati ORCID, Joulia Larionova
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This paper is available in a repository.

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Abstract

The autocatalytic sonochemical reaction of Fe(CO)(5) decomposition in [BuMeIm][Tf(2)N] provides iron nanoparticles in higher yields than in tetralin. Such a difference is explained by the higher decomposition of the intermediate Fe(3)(CO)(12) according to the two-sites model of the sonochemical reactions and the specific properties of the ionic liquid.