Published in
Royal Society of Chemistry, Chemical Communications, 26(52), p. 4804-4807, 2016
DOI: 10.1039/c6cc00498a
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A 3D MOF constructed from dysprosium(iii) oxalate and capping ligands: ferromagnetic coupling and field-induced two-step magnetic relaxation
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Abstract
A novel 3D MOF based on dysprosium(III) oxalate and 1,10-phenanthroline(phen), {[Dy(C2O4)1.5phen]∙0.5H2O}n (1), has been hydrothermally synthesized. The Dy3+ ion acts as a typical Y-shaped node, linking to each other to generate an interesting 3D topology structure. Complex 1 is the first 3D DyMOF displaying both ferromagnetic coupling and field-induced two-step magnetic relaxation.