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Royal Society of Chemistry, Dalton Transactions, 38(42), p. 13806, 2013

DOI: 10.1039/c3dt51863a

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Organosilicon linkers in metal organic frameworks: The tetrahedral tetrakis(4-tetrazolylphenyl)silane ligand

Journal article published in 2013 by Ivan Timokhin, Júlia Baguña Torres, Julia Baguna Torres, Andrew J. P. White, Paul D. Lickiss ORCID, Claudio Pettinari ORCID, Robert P. Davies
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This paper is available in a repository.

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Abstract

Formal substitution of the central carbon by silicon within the tetrahedral tetrakis(4-tetrazolylphenyl)methane linker in a copper-based MOF is shown to uniquely influence the structure of the resultant MOF, affecting the orientation of the metal-based nodes and leading to an increase in unit-cell volume and solvent accessible void space.