Royal Society of Chemistry, Physical Chemistry Chemical Physics, 13(16), p. 6139, 2014
DOI: 10.1039/c3cp54896a
Full text: Unavailable
Outer Co(ii) species in Co-ZIF-67 coordinate molecular oxygen both from the gas phase and liquid water, through an adsorption process (presumably yielding in both cases surface superoxo species), respectively weak and reversible (gas phase), and strong and irreversible (liquid); in the latter case desorption is however brought about by illumination with solar light comprising the UV component.