Published in
Royal Society of Chemistry, Journal of the Chemical Society, Chemical Communications, 24, p. 1168
DOI: 10.1039/c39790001168
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Carbon monoxide transfer to a metal co-ordinated carbyne ligand: X-ray crystal structure of [Mn2{µ-C(CO)C6H4-Me-p}(CO)6(η-C5H5)]·0·5Et2O
Journal article published in 1979 by
Jesús Martin-Gil 
,
Judith A. K. Howard,
Rafael Navarro,
F. Gordon A. Stone
,
Judith A. K. Howard,
Rafael Navarro,
F. Gordon A. Stone
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Abstract
The mononuclear cationic carbyne complexes [MC·C6H4Me-p-(CO)2(η-C5H5)]BF4(M = Mn or Re) react with [(Ph3P)2N][Mn(CO)5] to give compounds [MMn{µ-C(CO)·C6H4Me-p}(CO)6(η-C5H5)]·0·5Et2O in which a CO ligand has transferred to the bridging group; the structure of the dimanganese compound has been established by X-ray crystallography.