Royal Society of Chemistry, Journal of Materials Chemistry A: materials for energy and sustainability, 46(3), p. 23283-23288, 2015
DOI: 10.1039/c5ta06658a
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Metal oxide based supercapacitors can provide much higher energy densities as compared with carbon-based ones. However, metal oxides are usually suffered from low power densities together with poor cycle life, which is a big barrier for their practical applications. In this work, purposely confined NiO nanoparticles has been deposited uniformly on a three-dimensional graphite foam-carbon nanotube forest substrate, giving rise to a well-integrated free-standing electrode (GF-CNT@NiO) with strong synergetic effects generated from nickel oxide and carbon support. The electrode with 57.6% mass content of NiO delievers a high specific capacity of 196.5 mAh g-1 and excellent cycling stability for 30 000 cycles. When coupled with a graphene-CNT paper anode, an asymmetric supercapacitor (GF-CNT@NiO//G-CNT) is assembled, which demonstrates excellent cycling ability (only 18.3% of the capacitance drop after 30 000 cycles) and high power density (1.06-7.14 kW kg-1), suggesting its great promise for advanced supercapacitors.