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Royal Society of Chemistry, Journal of Materials Chemistry A: materials for energy and sustainability, 5(4), p. 1953-1961, 2016

DOI: 10.1039/c5ta10091g

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Efficient bifacial dye-sensitized solar cells through disorder by design

This paper is available in a repository.
This paper is available in a repository.

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Abstract

Herein we realize an optical design that optimizes the performance of bifacial solar cells without modifying any of the usually employed components. In order to do so, dielectric scatterers of controlled size and shape have been successfully integrated in the working electrodes of dye-sensitized solar cells (DSSCs), resulting in bifacial devices of outstanding performance. Power conversion efficiencies (PCEs) as high as 6.7% and 5.4% have been attained under front and rear illumination, respectively, which represent a 25% and a 33% PCE enhancement with respect to an 8 mm-thick standard solar cell electrode using platinum as the catalytic material. The remarkable bifacial character of our approach is demonstrated by the high rear/front efficiency ratio attained, around 80%, which is among the largest reported for this sort of device. The proposed optimized design is based on a Monte Carlo approach in which the multiple scattering of light within the cell is fully accounted for. We identified that the spherical shape of the scatterers is the key parameter controlling the angular distribution of the scattering, the most efficient devices being those in which the inclusions provide a narrow forward-oriented angular distribution of the scattered light. ; Funding for the development of the research leading to these results was received from the European Research Council under the European Union's Seventh Framework Programme (FP7/2007-2013)/ERC grant agreement no. 307081 (POLIGHT) and the Spanish Ministry of Economy and Competitiveness under grant MAT2014-54852-R. JMMM acknowledges the Spanish Ministry of Education, Culture and Sport for the funding through an FPU program. AJS acknowledges the Spanish Ministry of Economy and Competitiveness for funding through an FPI program under the project MAT2011–23593. YL acknowledges the funding from the People Programme (Marie Curie Actions) of the European Union's Seventh Framework Programme FP7/2007-2013/under REA grant agreement no. 622533. ; We acknowledge support by the CSIC Open Access Publication Initiative through its Unit of Information Resources for Research (URICI) ; Peer reviewed