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Royal Society of Chemistry, Chemical Communications, 45(48), p. 5653

DOI: 10.1039/c2cc17835d

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Photomagnetic effect in a cyanide-bridged mixed-valence {FeII2FeIII2} molecular square

Journal article published in 2012 by Yanling Li, Abhishake Mondal, Patrick Herson, Mannan Seuleiman, Marie-Laure Boillot, Eric Rivière ORCID, Miguel Julve, Lionel Rechignat, Azzedine Bousseksou, Rodrigue Lescouëzec ORCID
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This paper is available in a repository.

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Abstract

The self-assembly of [Fe(III)(Tp)(CN)(3)](-) and [Fe(II)(bik)(2)(S)(2)](2+) affords the cyanide-bridged mixed valence {Fe(III)(2)Fe(II)(2)}(2+) molecular square, which exhibits a photomagnetic effect under laser light irradiation at low temperature and also shows thermal spin-state conversion near ambient temperature.