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Royal Society of Chemistry, Organic and Biomolecular Chemistry, 17(10), p. 3357

DOI: 10.1039/c2ob06731e

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Making expensive dirhodium(ii) catalysts cheaper: Rh(ii) recycling methods

Journal article published in 2012 by Nuno R. Candeias ORCID, Carlos A. M. Afonso, Pedro M. P. Gois ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Dirhodium(II) catalysts have been widely used as a remarkable tool in organic synthesis, ultimately resulting in a myriad of transformations and formation of a wide variety of compounds, every so often intermediaries in drug synthesis. Aiming at a more sustainable chemistry, several methods suitable for the reutilisation of expensive dirhodium complexes have been developed. Herein, we provide a combined overview of the available methods for recovering and reusing dirhodium(II) metal complexes in catalysis, covering homogeneous catalysis as well as heterogenisation methods.