Published in

Royal Society of Chemistry, Dalton Transactions, 39(43), p. 14766-14771

DOI: 10.1039/c4dt02205j

Links

Tools

Export citation

Search in Google Scholar

Multifunctional MOFs through CO<sub>2</sub>fixation: a metamagnetic kagome lattice with uniaxial zero thermal expansion and reversible guest sorption

Journal article published in 2014 by Tony D. Keene, Michael J. Murphy, Jason R. Price ORCID, Natasha F. Sciortino, Peter D. Southon ORCID, Cameron J. Kepert
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

Full text: Unavailable

Green circle
Preprint: archiving allowed
Upload
Orange circle
Postprint: archiving restricted
Upload
Red circle
Published version: archiving forbidden
Policy details
Data provided by SHERPA/RoMEO

Abstract

The properties of atmospheric CO2 fixation, metamagnetism, reversible guest adsorption and zero thermal expansion have been combined in a single robust MOF, [Cu3(bpac)3(CO3)2](ClO4)2·H2O (·H2O). This compound is a ditopically-bridged copper carbonate kagome lattice where desolvation of the MOF allows subtle tuning of the metamagnetic and uniaxial ZTE behaviour.