Published in
Royal Society of Chemistry, Chemical Communications, 47, p. 6381
DOI: 10.1039/b813222d
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A snapshot of a coordination polymer self-assembly process: The crystallization of a metastable 3D network followed by the spontaneous transformation in water to a 2D pseudopolymorphic phase
Journal article published in 2008 by
Thierry Bataille,
Ferdinando Costantino,
Andrea Ienco 
,
Annalisa Guerri ,
Fabio Marmottini,
Stefano Midollini
,
Annalisa Guerri ,
Fabio Marmottini,
Stefano Midollini
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Abstract
A metastable copper(II) 3D hybrid with 4,4'-bipyridine (4,4'-bipy) and P,P'-diphenylethylenediphosphinate (pc2p(2-)) undergoes a spontaneous, quantitative, transformation to a stable 2D polymorphic species either spontaneously in water, or after thermal dehydration followed by hydration.