Published in
Royal Society of Chemistry, Chemical Communications, 13(52), p. 2792-2794, 2016
DOI: 10.1039/c5cc09780k
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Ion Flow in a Zeolitic Imidazolate Framework Results in Ionic Diode Phenomena
Journal article published in 2016 by
Elena Madrid,
Mark A. Buckingham,
James M. Stone,
Adrian T. Rogers,
William J. Gee,
Andrew D. Burrows 
,
Paul R. Raithby,
Veronica Celorrio ,
David J. Fermin,
Frank Marken
,
Paul R. Raithby,
Veronica Celorrio ,
David J. Fermin,
Frank Marken
This paper is available in a repository.
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Abstract
Ionic transport (for applications in nanofluidics or membranes) and "ionic diode" phenomena in a zeolitic imidazolate framework (ZIF-8) are investigated by directly growing the framework from aqueous Zn 2+ and 2-methylimidazole as an "asymmetric plug" into a 20 μm diameter pore in a ca. 6 μm thin poly-ethylene-terephthalate (PET) film.