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Royal Society of Chemistry, Dalton Transactions, 46(40), p. 12450
DOI: 10.1039/c1dt11451d
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New seven membered palladacycles: C-Br bond activation of 2-bromo-pyridine derivative by Pd(II)
Journal article published in 2011 by
Juan Nicasio-Collazo 
,
Eleuterio Álvarez ,
José C. Alvarado Monzón,
Gabriel Andreu-De-Riquer,
Gabriel Andreu de-Riquer,
J. Oscar C. Jimenez-Halla ,
J. Oscar C. Jimenez Halla,
Luis M. De León Rodríguez ,
Gabriel Merino,
Ubaldo Morales,
Oracio Serrano,
Jorge A. López
,
Eleuterio Álvarez ,
José C. Alvarado Monzón,
Gabriel Andreu-De-Riquer,
Gabriel Andreu de-Riquer,
J. Oscar C. Jimenez-Halla ,
J. Oscar C. Jimenez Halla,
Luis M. De León Rodríguez ,
Gabriel Merino,
Ubaldo Morales,
Oracio Serrano,
Jorge A. López
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Abstract
C-Br bond activation followed by a C-C coupling reaction of the 2-bromo-pyridyl unit of [1-phenyl-2-(6-bromopyridin-2-yl)-benzoimidazole] was performed by Pd(CH(2)CMe(2)-o-C(6)H(4))(η(4)-COD). Two new seven membered palladacycles were obtained. A combined experimental and theoretical DFT study elucidates the mechanism for this reaction.