Published in
Royal Society of Chemistry, Dalton Transactions, 48, p. 6880
DOI: 10.1039/b817893n
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Dimethylalkoxygallane incorporating a donor-functionalised alkoxide: The monomeric gas-phase structure
Journal article published in 2008 by
Caroline E. Knapp,
Claire J. Carmalt 
,
Paul F. McMillan,
Derek A. Wann,
Heather E. Robertson,
David W. H. Rankin
,
Paul F. McMillan,
Derek A. Wann,
Heather E. Robertson,
David W. H. Rankin
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Abstract
The structure of the vapour produced upon heating the dimethylalkoxygallane [Me(2)GaOCH(2)CH(2)NMe(2)](2) has been studied by gas-phase electron diffraction and ab initio molecular orbital calculations; only the monomeric form [Me(2)GaOCH(2)CH(2)NMe(2)] is observed in the vapour, with the nitrogen atom forming a dative bond with the metal centre.