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Royal Society of Chemistry, Chemical Communications, 70(50), p. 10055-10058

DOI: 10.1039/c4cc03764b

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A zirconium squarate metal-organic framework with modulator-dependent molecular sieving properties

Journal article published in 2014 by Bart Bueken, Helge Reinsch, Nele Reimer, Ivo Stassen ORCID, Frederik Vermoortele, Rob Ameloot ORCID, Norbert Stock, Christine E. A. Kirschhock, Dirk De Vos
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

We report the first zirconium metal-organic framework based on squaric acid, representing the member with the smallest unit cell in the isoreticular UiO-66 family. Its molecular sieving properties are strongly influenced by the monocarboxylic acid modulator incorporated during synthesis.