Royal Society of Chemistry, Chemical Communications, 70(50), p. 10055-10058
DOI: 10.1039/c4cc03764b
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We report the first zirconium metal-organic framework based on squaric acid, representing the member with the smallest unit cell in the isoreticular UiO-66 family. Its molecular sieving properties are strongly influenced by the monocarboxylic acid modulator incorporated during synthesis.