Published in
Royal Society of Chemistry, Chemical Communications, 56(49), p. 6340
DOI: 10.1039/c3cc42125b
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Abrupt spin crossover in an iron(III) quinolylsalicylaldimine complex: structural insights and solvent effects
Journal article published in 2013 by
David J. Harding 
,
Wasinee Phonsri,
Phimphaka Harding ,
Ian A. Gass,
Keith S. Murray,
Boujemaa Moubaraki,
John D. Cashion,
Lujia Liu,
Shane G. Telfer
,
Wasinee Phonsri,
Phimphaka Harding ,
Ian A. Gass,
Keith S. Murray,
Boujemaa Moubaraki,
John D. Cashion,
Lujia Liu,
Shane G. Telfer
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Abstract
The first Fe(iii) qsal-X complex exhibiting abrupt complete spin crossover at 228 K with a hysteresis of 8 K, [Fe(qsal-I)2]OTf is reported. Structural studies of the MeOH solvate in the LS and HS state and at the spin transition are described.