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Royal Society of Chemistry, Chemical Communications, 79(51), p. 14724-14727

DOI: 10.1039/c5cc05913e

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A vanadium(IV) pyrazolate metal-organic polyhedron with permanent porosity and adsorption selectIVity

Journal article published in 2015 by Adam Wiktor Augustyniak, Marzena Fandzloch ORCID, Maria Domingo-Garcia, Iwona Łakomska, Jorge A. R. Navarro ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

A vanadium(IV) pyrazolate-based open metal organic polyhedron of [V3(μ3-O)O(OH)2(μ4-BPD)1.5(μ-HCOO)3] (BDP = benzene-1,4-bipyrazolate) formulation gives rise to a porous crystal structure exhbiting micro and mesoporosity which is useful for selective adsorption of CO2 over N2 and benzene over cyclohexane.