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Royal Society of Chemistry, Green Chemistry, 2(15), p. 330

DOI: 10.1039/c2gc36797a

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More efficient redox biocatalysis by utilising 1,4-butanediol as a ‘smart cosubstrate’

Journal article published in 2013 by Selin Kara, Dominik Spickermann, Joerg H. Schrittwieser, Christian Leggewie, Willem J. H. van Berkel ORCID, Isabel W. C. E. Arends, Frank Hollmann
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

1,4-Butanediol is shown as an efficient cosubstrate to promote NAD(P)H-dependent redox biocatalysis. The thermodynamically and kinetically inert lactone coproduct makes the regeneration reaction irreversible. Thereby not only the molar surplus of cosubstrate is dramatically reduced but also faster reaction rates are obtained.