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Royal Society of Chemistry, Journal of the Chemical Society, Chemical Communications, 21, p. 1576

DOI: 10.1039/c39910001576

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Stereocontrolled total synthesis of galactostatin from serine

Journal article published in 1991 by Alessandro Dondoni, Pedro Merino, Daniela Perrone ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

An efficient stereoselective total synthesis of (-)-galactostatin [(-)-I] from N-tert-butoxycarbonyl-2,3-isopropylidene L-serine Me ester (II) (21% overall yield) via thiazole intermediates serving as protected aldehydes is described. The parallel synthesis of the natural antipole (+)-I starts from D-serine. [on SciFinder (R)]