Royal Society of Chemistry, Chemical Communications, 21, p. 2417
DOI: 10.1039/b800055g
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This article summarizes experimental and theoretical evidence for the existence of four distinct binding modes for complexes of anions with charge-neutral arenes. These include C-H hydrogen bonding and three motifs involving the arene-pi system-the noncovalent anion-pi interaction, weakly covalent sigma interaction, and strongly covalent sigma interaction.