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Royal Society of Chemistry, Chemical Communications, 21, p. 2417

DOI: 10.1039/b800055g

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Anion–arene adducts: C–H hydrogen bonding, anion–π interaction, and carbon bonding motifs

Journal article published in 2008 by Benjamin P. Hay, Vyacheslav S. Bryantsev ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

This article summarizes experimental and theoretical evidence for the existence of four distinct binding modes for complexes of anions with charge-neutral arenes. These include C-H hydrogen bonding and three motifs involving the arene-pi system-the noncovalent anion-pi interaction, weakly covalent sigma interaction, and strongly covalent sigma interaction.