Published in
Royal Society of Chemistry, Chemical Communications, 10(49), p. 990-992, 2013
DOI: 10.1039/c2cc38176a
Links
Tools
A reagentless thermal post-synthetic rearrangement of an allyloxy-tagged metal-organic framework
Journal article published in 2012 by
Andrew D. Burrows 
,
Sally O. Hunter,
Mary F. Mahon,
Christopher Richardson
,
Sally O. Hunter,
Mary F. Mahon,
Christopher Richardson
This paper is available in a repository.
Full text: Download
Published version:
archiving forbidden
Data provided by 
Abstract
Direct heating of a metal-organic framework provides a simple, controllable way of effecting a covalent post-synthetic modification. Herein we report that an allyloxy-tagged zinc metal-organic framework undergoes a thermally-promoted aromatic Claisen rearrangement through which the framework connectivity and porosity are maintained.