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Royal Society of Chemistry, Journal of Materials Chemistry C Materials for optical and electronic devices, 30(3), p. 7916-7924, 2015

DOI: 10.1039/c5tc01174d

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Critical assessment of the nature and properties of Fe(ii) triazole-based spin-crossover nanoparticles

Journal article published in 2015 by C. Bartual-Murgui, E. Natividad, O. Roubeau ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Nanoparticles of the compound [Fe(Htrz)2trz]BF4 are shown to have a rod shape. Their size is found to control the width of the thermal hysteresis displayed in the spin crossover of this material, while the removal of surfactant results systematically in a reduction of the hysteresis width, by up to 16 K, both effects being original and important for potential applications.