Published in
Royal Society of Chemistry, Dalton Transactions, 25(42), p. 9148, 2013
DOI: 10.1039/c3dt33082f
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Preparation of phosphine-functionalized polystyrene stars by metal catalyzed controlled radical copolymerization and their application to hydroformylation catalysis
Journal article published in 2013 by
Andrés F. Cardozo,
Eric Manoury,
Carine Julcour,
Jean-François Blanco,
Henri Delmas,
Florence Gayet,
Rinaldo Poli 
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Abstract
Well defined star copolymers have been prepared by copper-catalyzed atom transfer radical copolymerization of styrene and styryldiphenylphosphine starting from a modified Boltorn[trade mark sign] H30 multifunctional initiator. These polymers and an analogue obtained by debromination of the arm ends with nBu3SnH have been used in combination with [Rh(acac)(CO)2] for the homogeneous phase hydroformylation of 1-octene.