Published in
Royal Society of Chemistry, Dalton Transactions, 29(44), p. 12970-12975, 2015
DOI: 10.1039/c5dt01846c
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AEE-active cyclic tetraphenylsilole derivatives with ∼100% solid-state fluorescence quantum efficiency
Journal article published in 2015 by
Yuanjing Cai,
Kerim Samedov,
Brian S. Dolinar 
,
Haley Albright,
Zhegang Song,
Chaocan Zhang,
Ben Zhong Tang,
Robert West,
Bob West
,
Haley Albright,
Zhegang Song,
Chaocan Zhang,
Ben Zhong Tang,
Robert West,
Bob West
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Abstract
Two new strongly AEE active (I/I0 ≈ 94) tetraphenylsilole-containing cyclosiloxanes with cyan emissions (λem = 500 nm) and ~100% solid state fluorescence quantum yields are reported. The intra- and intermolecular C-H•••π interactions in the crystal play a major role in the observed high solid state fluorescence quantum yields.