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Royal Society of Chemistry, Dalton Transactions, 26(44), p. 11977-11983, 2015

DOI: 10.1039/c5dt01716e

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Mechanism of proton transfer to coordinated thiolates: encapsulation of acid stabilizes precursor intermediate

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Hydrogen bonded intermediate in protonation of [Ni(thiolate)(triphos)]+ by 2,6-lutidinium is stabilized by encapsulation of the acid by phenyl groups of triphos.