Published in
Royal Society of Chemistry, Dalton Transactions, 24(44), p. 10947-10951
DOI: 10.1039/c5dt01338k
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Synthesis and structural characterization of BINOL-modified chiral polyoxometalates
Journal article published in 2015 by
Ryo Ishimoto,
Keigo Kamata,
Kosuke Suzuki 
,
Kazuya Yamaguchi ,
Noritaka Mizuno
,
Kazuya Yamaguchi ,
Noritaka Mizuno
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Abstract
Chiral ligand-modified polyoxometalates (POMs) were successfully synthesized by introduction of BINOL into the dititanium-substituted POM in an organic medium and characterized by the X-ray crystallographic, spectroscopic, and elemental analysis. These BINOL-modified POMs were stable in the solution state and showed catalytic activity for asymmetric oxidation of thioanisole.