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Royal Society of Chemistry, Dalton Transactions, 24(44), p. 11119-11128

DOI: 10.1039/c5dt01320h

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Imido-pyridine Ti(iv) compounds: synthesis of unusual imido–amido heterobimetallic derivatives

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Controlled generation of novel bridging or terminal imido-pyridine complexes is achieved, including the unusual species [Li(THF)][Ti(η5-C5Me5)(NR)(NHR)2]. Computational studies corroborate its charge-separated nature.