Royal Society of Chemistry, Dalton Transactions, 17(44), p. 8169-8177
DOI: 10.1039/c5dt00312a
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In the presence of a bulky N-heterocyclic carbene, Zn(HMDS)2can be converted in to either a mononuclear amido/hydride complex or a tetranuclear hydride rich cluster depending on the hydride source and reaction conditions employed.