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Royal Society of Chemistry, Chemical Communications, 40(51), p. 8421-8424

DOI: 10.1039/c5cc00113g

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Separation of polar compounds using a flexible metal–organic framework

Journal article published in 2015 by Radha Kishan Motkuri ORCID, Praveen K. Thallapally ORCID, Harsha V. R. Annapureddy, Liem X. Dang, Rajamani Krishna, Satish K. Nune ORCID, Carlos A. Fernandez, Jian Liu, B. Peter McGrail, B. Peter McGrail
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This paper is available in a repository.

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Abstract

A flexible metal-organic framework constructed from a flexible linker is shown to possess the capability of separating mixtures of polar compounds (propanol isomers) by exploiting the differences in the saturation capacities of the constituents. Transient breakthrough simulations show that these sorption-based separations are in favor of the component with higher saturation capacity.