Published in

Royal Society of Chemistry, Dalton Transactions, 7(39), p. 1719-1721, 2010

DOI: 10.1039/b914330k

Links

Tools

Export citation

Search in Google Scholar

Unprecedented three-step spin-crossover transition in new 2-dimensional coordination polymer{FeII(4-methylpyridine)2[AuI(CN)2]2}

Journal article published in 2010 by Takashi Kosone, Itaru Tomori, Chikahide Kanadani, Toshiaki Saito, Tomoyuki Mochida ORCID, Takafumi Kitazawa
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

Full text: Unavailable

Green circle
Preprint: archiving allowed
Upload
Orange circle
Postprint: archiving restricted
Upload
Red circle
Published version: archiving forbidden
Policy details
Data provided by SHERPA/RoMEO

Abstract

A new spin crossover (SCO) coordination polymer, {[Fe(II)(4-methylpyridine)(2)][Au(I)(CN)(2)](2)}(n) () has been synthesized. The complex () has been observed to have a thermal induced three-step SCO transition, which is unprecedented behavior as compared with existing SCO complexes. In the complex, about 18%, 41% and 41% high spin states are changed to low spin states in the first-step, second-step and third-step, respectively.