Published in
Royal Society of Chemistry, Organic and Biomolecular Chemistry, 4(7), p. 706-716, 2009
DOI: 10.1039/b815737e
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Synthesis of new aza-analogs of staurosporine, K-252a and rebeccamycin by nucleophilic opening of C<sub>2</sub>-symmetric bis-aziridines
Journal article published in 2009 by
Sandrine Delarue-Cochin,
Isabelle McCort-Tranchepain 
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Abstract
Stable, water-soluble aminosugar staurosporine, K-252a and rebeccamycin analogs have been prepared by nucleophilic opening of C(2)-symmetric N-activated bis-aziridines by bis-indolylmaleimides. This divergent strategy allows the synthesis of unsymmetrical substituted derivatives and provides an easy access to the piperidine and pyrrolidine analogs.