Published in
Royal Society of Chemistry, Chemical Communications, 3, p. 225-227, 2007
DOI: 10.1039/b614575b
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Cavity effect amplification in the recognition of dicarboxylic acids by initial ditopic H-bond formation followed by kinetic trapping
Journal article published in 2007 by
Peter R. Brotherhood,
Richard A.-S. Wu,
Peter Turner,
Maxwell J. Crossley 
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Abstract
Di[dihydroxotin(IV)] Tröger's base bis-porphyrin 1, a host molecule with two internal and two external guest interaction sites, binds <or= 1 equivalent of dicarboxylic acid quantitatively within the chiral cavity, a regioselectivity amplified by initial ditopic H-bond formation, followed by kinetic trapping.