Published in

Royal Society of Chemistry, Chemical Communications, 72(49), p. 7914

DOI: 10.1039/c3cc44077j

Links

Tools

Export citation

Search in Google Scholar

A Lewis acid catalytic core sandwiched by inorganic polyoxoanion caps: selective H2O2-based oxidations with [AlIII4(H2O)10(β-XW9O33H)2]6− (X = AsIII, SbIII)

Journal article published in 2013 by Mauro Carraro ORCID, Bassem S. Bassil, Antonio Soraru, Serena Berardi, Andreas Suchopar, Ulrich Kortz, Marcella Bonchio
This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
Upload
Orange circle
Postprint: archiving restricted
Upload
Red circle
Published version: archiving forbidden
Policy details
Data provided by SHERPA/RoMEO

Abstract

The Al-III-containing polyanions [Al-4(III)(H2O)(10)(beta-XW9O33H)(2)](4-) with X=As-III (1) and Sb-III (2) feature four aluminum(III) centers sandwiched by two trivacant (beta-XW9O33) Keggin units, and trigger peroxide catalysis as well as substrate coordination via multiple Lewis acid site interactions.