Published in
Royal Society of Chemistry, Chemical Communications, 33(51), p. 7124-7127, 2015
DOI: 10.1039/c5cc00853k
Links
Tools
Butadiene from acetylene ethylene cross metathesis
Journal article published in 2015 by
Ioan-Teodor Trotuș,
Tobias Zimmermann,
Nicolas Duyckaerts,
Jan Geboers,
Ferdi Schüth
This paper was not found in any repository, but could be made available legally by the author.
Full text: Unavailable
Published version:
archiving forbidden
Data provided by 
Abstract
Acetylene to butadiene direct synthesis, via enyne cross-metathesis, is demonstrated with commercial ruthenium carbene catalysts. Using excess of ethylene, yields greater than 50% are obtained. High activity is observed in the first minute of the reaction (TOF>800 h-1 based on butadiene). Catalyst reusability and poisoning are discussed.