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Royal Society of Chemistry, Chemical Communications, 26(51), p. 5735-5738

DOI: 10.1039/c5cc00686d

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Photocatalytic CO 2 reduction by a mixed metal (Zr/Ti), mixed ligand metal–organic framework under visible light irradiation

Journal article published in 2015 by Yeob Lee, Sangjun Kim, Jeung Ku Kang, Seth M. Cohen ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Postsynthetic exchange (PSE) of Ti(IV) into a Zr(IV)-based MOF enabled photocatalytic CO2 reduction to HCOOH under visible light irradiation with the aid of BNAH and TEOA. Use of a mixed-ligand strategy enhanced the photocatalytic activity of the MOF by introducing new energy levels in the band structure of the MOF.