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Royal Society of Chemistry, Chemical Communications, 30(48), p. 3593, 2012

DOI: 10.1039/c2cc17431f

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Enhanced photocurrent production from thin films of Ru(II) metallopolymer/Dawson polyoxotungstate adducts under visible irradiation

Journal article published in 2012 by James J. Walsh ORCID, Colm T. Mallon, Alan M. Bond, Tia E. Keyes ORCID, Robert J. Forster
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Thin films of polyoxometalates that are sensitized with a Ru(II) metallopolymer generate significant photocurrents in the presence of benzyl alcohol and visible light. Significantly, the photocurrent generated by the tungstate based adduct, α-[P(2)W(18)O(62)](6-), is approximately seven fold larger than that found for the Dawson polyoxomolybdate α-[S(2)Mo(18)O(62)](4-).