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Royal Society of Chemistry, Dalton Transactions, 12(42), p. 4110-4113, 2013

DOI: 10.1039/c2dt32441e

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Solvent effects on Grubbs’ pre-catalyst initiation rates

Journal article published in 2013 by Ian W. Ashworth, David J. Nelson ORCID, Jonathan M. Percy
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Initiation rates for Grubbs and Grubbs-Hoveyda second generation pre-catalysts have been measured accurately in a range of solvents. Solvatochromic fitting reveals different dependencies on key solvent parameters for the two pre-catalysts, consistent with different mechanisms by which the Grubbs and Grubbs-Hoveyda pre-catalysts initiate.